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Notes
What is meant by crystal field splitting energy ? On the basis of crystal field theory, write the electronic configuration of d4 in terms of t2g and eg in an octahedral field when, CBSE- Class12- Chemistry 2013
(ii)∆0< P
(i) Δ0 > P
t4 2g eg0
(ii) Δ0 < P
t3 2g eg1
In an octahedral complex, the d orbitals of the central metal ion divide into two sets of different energies. The separation in energy is the crystal field splitting energy, Δ. (A) When Δ is large, it is energetically more favourable for electrons to occupy the lower set of orbitals.
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